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夏建龙

更新日期:2016-04-06

 

 

夏建龙 博士,教授,博士生导师

 

性别:      出生年月:198412月(农历)

联系地址:材料复合新技术国家重点实验室
武汉市洪山区珞狮路122号武汉理工大学马房山校区 430070

邮箱: jlxia@whut.edu.cn 

 

招生方向:材料物理与化学、有机化学、高分子化学与物理等(欢迎化学、材料及物理等相关背景的同学加入我们课题组!

 

研究工作经历:

20151月至今,武汉理工大学材料复合新技术国家重点实验室,教授

201412月至今,武汉理工大学化学化工与生命科学学院,教授

2012.07-2014.12,美国哥伦比亚大学化学系,博士后

2011.07-2012.06, 美国波士顿大学化学系,博士后

2013.04-2013.05, 美国劳伦斯伯克利国家实验室,访问学者

2010.09-2010.11,英国杜伦大学化学系,访问学生

 

教育经历:

2006.09-2011.06, 华中师范大学化学学院,博士

 

研究简介:

先后在美国波士顿大学、哥伦比亚大学和美国劳伦斯伯克利国家实验室从事博士后及访问合作研究。入选湖北省优秀青年骨干人才、楚天学子在单线态裂分(Singlet Fission)、单分子导线、分子整流器及碳纳米管的导向合成等方面取得了创新性成果。提出了高效的分子内单线态裂分材料的设计思路,所设计材料的三线态激子产率达到170%。实现了分子导线中电子导电和空穴导电的有效调控,制备了最高整流率达500,平均整流率超过200的单分子整流器。首次完成了碳纳米管导向合成模板单元的克级制备。现已在Nature MaterialsNature NanotechnologyNature Chemistry等国际权威期刊发表SCI论文40余篇,论文被引用1500余次。研究成果被C&EN NewsScienceDaily和纳米科技网(Nanotech Web)等20多家专业媒体亮点报道。申请美国专利2项(授权1项)。目前主要致力于有机/高分子材料在光电器件(有机场效应晶体管、有机太阳能电池和单分子电子器件等)中的应用研究,具体研究方向主要包括:有机半导体材料的单线态裂分、有机/高分子光电材料的合成、光电器件的制备与表征、单分子导线以及高分子化学与物理。

 

学术荣誉及兼职:

湖北省优秀青年骨干人才(2015

湖北省楚天学子

《中国化学快报》青年编委会, 2017-至今。

中国材料研究学会青委会理事

 

主要科研项目

国家自然科学基金面上项目(51773160),2018-2021

国家自然科学基金青年基金(21502147),2016-2018

武汉市晨光计划

 

 

代表性论文

1. Borges, A.; Xia, J.-L.; Liu, S. H.; Venkataraman, L.; Solomon, G. C. The role of through-space interactions in modulating constructive and destructive interference effects in benzene. Nano Lett. 2017, 17, 4436-4442.

2. Xia, J.-L.; Busby, E.; Sanders, S. N.; Tung, C.; Cacciuto, A.; Sfeir, M. Y.; Campos, L. M. Influence of Nanostructure on the Exciton Dynamics of Multichromophore DonorAcceptor Block Copolymers. ACS Nano. 2017, 11, 4593–4598.

3. Xia, J.-L.; Jiang, L. Nano. Res. 2017, 10, 1115–1124.

4. Xia, J.-L.*; Sanders, S. N.; Cheng, W.; Low, J. Z.; Liu, J.; Campos, L. M.; Sun, T. Singlet Fission: Progress and Prospects in Solar Cells.  Adv. Mater. 2017, 29, 1601652.

5. Zuo, W.; Li, R.; Zhou, C.; Li, Y.; Xia, J.-L.; Liu, J. Adv. Sci. 2017, 1600539

6. Capozzi, B.; Low, J. Z.; Xia, J.-L.; Liu, Z.-F.; Neaton, J. B.; Campos, L. M.; Venkataraman, L. Mapping the Transmission Function of Single-Molecule Junctions. Nano Lett. 2016, 16, 3949-3954.

7. Busby, E. J.; ‡ Xia, J.-L.; (共同一作) Wu, Q.; Low, J. Z.; Song, R.; Miller, J. R.; Zhu, X.-Y.; Campos, L. M.; Sfeir, M. Y. A Design Strategy for Intramolecular Singlet Fission Mediated by Charge-Transfer States in Donor-Acceptor Organic Materials. Nat. Mater. 2015, 14, 426-433.

8. Capozzi, B.; Xia, J.-L.; Adak, O.; Dell, E. J.; Liu, Z.-F.; Taylor, J. C.; Neaton, J. B.; Campos, L. M.; Venkataraman, L. Single-Molecule Diodes with High Rectification Ratios Through Environmental Control. Nat. Nanotech. 2015, 10, 522-527. 

9. Dell, E. J.; Capozzi, B.; Xia, J.-L.; Venkataraman, L.; Campos, L. M. Molecular Length Dictates the Nature of Charge Carriers in Single-Molecule Junctions. Nat. Chem. 2015, 7, 209-214. 

10. Sanders, S. N.; Kumarasamy, E.; Pun, A. B.; Trinh, M. T.; Choi, B.; Xia, J.-L.; Taffet, E. J.; Low, J. Z.; Miller, J. R.; Roy, X.; Zhu, X.-Y.; Steigerwald, M. L.; Sfeir, M. Y.; Campos, L. M. Quantitative Intramolecular Singlet Fission in Bipentacenes. J. Am. Chem. Soc. 2015, 137, 8965-8972.

11. Busby, E.; Xia, J.-L.; Low, J. Z.; Wu, Q.; Hoy, J.; Campos, L. M.; Sfeir, M. Y. Fast Singlet Exciton Decay in Push-Pull Molecules Containing Oxidized Thiophenes. J. Phys. Chem. B 2015, 119, 7644-7650.

12. Xia, J. -L.; Capozzi, B.; Wei, S.; Strange, M.; Batra, A.; Moreno, J. R.; Amir, E.; Amir, R. J.; Solomon, G. C.; Venkataraman, L.*; Campos, L. M.* Breakdown of Interference Rules in Azulene, a Non-Alternant Hydrocarbon. Nano Lett. 2014, 14, 2941. 

Featured in NanoTechWeb.org.  

Highlighted in Nature Nanotechnology (doi:10.1038/nnano.2014.121).

13. Xia, J.-L.;* Ou, Y-P.; Meng, X.-G.; Jin, G.-J.; Yin, J.; Yu, G.-A.; Liu, S. H.* Synthesis and Characterization of Dithia[3.3]metaparacyclophane Bridged Bimetallic Ruthenium Acetylide Complexes. Eur. J. Inorg. Chem. 2014, 247-255.

14. Wei, S.; Xia, J.-L; Dell, E. J.; Jiang, Y.; Song, R.; Lee, H.; Rodenbough, P.; Briseno, A. L.; Campos, L. M. Bandgap Engineering through Controlled Oxidation of Polythiophenes. Angew. Chem. Int. Ed. 2014, 53, 1832-1836. 

15. Alvarez, M. P.; Burrezo, P. M.; Kertesz, M.; Yamago, S.; Xia, J.; Jasti, R.; López Navarrete, J. T.; Taravillo, M.; Baonza, V. G.; Casado, Juan. Angew. Chem. Int. Ed. 2014, 53, 7033. 

16. Reddy, V S.; Camacho, C.; Xia, J.-L.; Jasti, R.; Irle, S. Quantum dynamics simulations reveal vibronic effects on the optical properties of [n] cycloparaphenylenes. J. Chem. Theory Comput. 2014, 10, 4025-4036. 

17. Xia, J.-L.;* Ou, Y-P.; Wu, D.; Jin, G.-J.; Yin, J.; Yu, G.-A.; Liu, S. H.* Dithia[3.3]paracyclophane-Bridged Bimetallic Ruthenium Acetylide Complexes : Synthesis, Structures and Influence of transannular π-π interactions on Their Electronic Properties. Dalton Trans. 2013, 42, 14212-14222.

18. Zabula, A. V.; Filatov, A. S.; Xia, J.-L.; Jasti, R.;* Petrukhina, M. A.* Tightening the Nanobelt Upon Multi-Electron Reduction. Angew. Chem. Int. Ed. 2013, 52, 5033-5036.

19. Ou, Y-P.; Xia, J.-L.; Zhang, J.; Xu, M.; Yin, J.; Yu, G.-A.; Liu, S. H.* Chem Asian J. 2013, 8, 2023-2032.

20. Zhu, X.; Ou, Y.; Zhang, J.; Xia, J.-L.; Yin, J.; Yu, G. A.; Liu, S. H.* Dalton Trans. 2013, 42, 7177-7189.

21. Xia, J.-L.; Jasti, R.* Synthesis, Characterization, and Crystal Structure of [6]Cycloparaphenylene. Angew. Chem. Int. Ed. 2012, 51, 2474.

Highlighted in Synfacts by Prof. Timothy M. Swager —“Synthesis of the Smallest Nanohoop”.

22. Xia, J.-L.; Golder, M. R.; Foster, M, E.; Wong, B.; Jasti, R.* "Synthesis, Characterization, and Computational Studies of Cycloparaphenylene Dimers." J. Am. Chem. Soc. 2012, 134, 19709-19715.

23. Xia, J.-L.; Bacon, J. W.; Jasti, R.* “Gram-Scale Synthesis and Crystal Structures of [8]- and [10]CPP, and the Solid-State Structure of C60@[10]CPP”. Chem. Sci. 2012, 3, 3018-3021.

Highlighted in C&E news (Jul. 18, 2012, page 9) “Nanohoops Scaled Up 100-fold”;

Highlighted in Synfacts by Prof. Timothy M. Swager —“Cycloparaphenylenes by the Gram”.

Top ten most accessed articles in July

24. Xia, J.-L.; Liu, S. H.;* Cozzi, F.; Mancinelli, M.; Mazzanti, A.* An Experimental Study of the Effect of Substituents on the Aromatic-Aromatic Interactions in Some Dithia-[3,3]-metaparacyclophanes. Chem. Eur. J. 2012, 18, 3611.

25. Xia, J.-L.; Man, W. Y., Zhu, X.; Zhang, C.; Jin, G.-J.; Schauer, P. A.; Fox, M. A.; Yin, J.; Yu, G.-A.; Low, P. J.;* Liu, S. H.* Synthesis and Characterization of Dithia[3.3]paracyclophane Bridged Binuclear Ruthenium Vinyl and Acetylide Complexes. Organometallics 2012, 31, 5321-5333.

26. Xia, J.-L.; Zhang, C.; Zhu, X.; Ou, Y.; Jin, G.-J.; Yu, G.-A.; Liu, S. H.* Substituted diethynyldithia[3.3]paracyclophanesA synthetically more accessible new building block for molecular scaffolding. New J. Chem. 2011, 35, 97–102.

27. Man, W. Y.; Xia, J.-L.; Brown, N. J.; Farmer, J. D.; Yufit, D. S.; Howard, J. A. K.; Liu, S. H.; Low, P. J.* Spectroscopic and Computational Studies of the Ligand Redox Non-Innocence in Mono- and Binuclear Ruthenium Vinyl Complexes. Organometallics, 2011, 30, 1852–1858.

28. Ou, Y.-P.; Jiang, C.; Wu, D.; Xia, J.-L.; Yin, J.; Jin, S.; Yu, G.-A.; Liu, S. H.* Organometallics, 2011, 30, 5763–5770.

29. Li, Z.; Xia, J.-L.; Liang, J.; Yuan, J.; Jin, G.; Yin, J.; Yu, G.-A.; Liu, S. H.* Dyes Pigments 2011, 90, 290296. 

30. Li, Z.; Lin, Y.; Xia, J.-L.; Zhang, H.; Fan, F.; Zeng, Q.; Feng, D.; Yin, J.; Liu, S. H.* Synthesis of novel diarylethene compounds containing two imidazole bridge units and tuning of their optical properties. Dyes Pigments 2011, 90, 245252.

31. Wu, X-H.; Liang, J-H.; Xia, J.-L.; Yin, J.; Jin, S.; Yu, G-A.; Liu, S. H.* Synthesis, characterization, and properties of binuclear ruthenium complexes with dendritic side chains on their bridges. Inorg. Chim. Acta. 2011, 370, 286-291.

32. Jin, G. J.; Chen, G.; Xia, J.-L.; Yin, J.; Yu, G.-A.; Liu, S. H.* Synthesis, characterization, and properties of conjugated binuclear bis-terpyridyl ruthenium complexes. Transition Met. Chem. 2011, 36, 611615. 

33. Wu, X.-H.; Liang, J. H.; Xia, J.-L.; Jin, S.; Yu, G.-A.; Liu, S. H.* Bimetallic Ruthenium Complexes: Synthesis, Characterization, and the Effect of Appending Long Carbon Chains to Their Bridges. Organometallics 2010, 29, 1150–1156.

34. Chen, G.; Xia, J.-L.; Li, Z.; Yu, G.-A.; Jin, S.; Liu, S. H.* J. Organomet. Chem. 2010, 695, 323–326.

35. Liu, F.; Wu, X.-H.; Xia, J.-L.; Jin, S.; Yu, G.-A.; Liu, S. H.* Synthesis and characterization of (CH=CH)n-bridged (n = 1, 2, 3) heterobimetallic and trimetallic ferrocene–ruthenium complexes. J. Organomet. Chem. 2010, 695, 809–815. 

36. Xia, J.-L.; Wu, X.-H.; Lu, Y.; Chen, G.; Jin, S.; Yu, G.-A. and Liu, S. H.* Synthesis and Characterization of Conjugated Diallenes and Their Binuclear Ruthenium η3-Allyl Complexes. Organometallics 2009, 28, 2701–2706. 

37. Xia, J.-L.; Xiong, W.-C.; Chen, G.; Yu, G.-A.; Jin, S.; Liu, S. H.* Reactions of [Cp*Ru(H2O)(NBD)]+ with diynes. Transition Met. Chem. 2009, 34, 389–393. 

 

 

专利

1. Jasti, R.*; Xia, J.-L. “[n]Cycloparaphenylenes (CPP), [n] Macrocycle intermediates and methods of making same.” PCT Int. Appl. (2013) WO2013112493 (PCT/US2013/022608).

2. Campos, L.; Sfeir, M. Y.; Xia, J.-L.; Busby, E. M. A. Organic Materials Capable of Multiple Exciton Generation. US patent. US Patent. 20170141318.